| CD1 The Devil You Know (Expanded Edition) |
| 1 | Atom and Evil |
| 2 | Fear |
| 3 | Bible Black |
| 4 | Double the Pain |
| 5 | Rock and Roll Angel |
| 6 | The Turn of the Screw |
| 7 | Eating the Cannibals |
| 8 | Follow the Tears |
| 9 | Neverwhere |
| 10 | Breaking into Heaven |
| 11 | The Devil Cried (Bonus Track - from The Dio Years) |
| 12 | Shadow of the Wind (Bonus Track - from The Dio Years) |
| 13 | Ear in the Wall (Bonus Track - from The Dio Years) |
| CD2 Live From Radio City Music Hall - Part 1 |
| 1 | E5150 / After All (The Dead) |
| 2 | The Mob Rules |
| 3 | Children of the Sea |
| 4 | Lady Evil |
| 5 | I |
| 6 | The Sign of the Southern Cross |
| 7 | Voodoo |
| 8 | The Devil Cried |
| CD3 Live From Radio City Music Hall - Part 2 |
| 1 | Computer God |
| 2 | Falling Off the Edge of the World |
| 3 | Shadow of the Wind |
| 4 | Die Young |
| 5 | Heaven and Hell |
| 6 | Lonely Is the Word |
| 7 | Neon Knights |
| CD4 Neon Nights: 30 Years of Heaven & Hell (Live at Wacken 2009) |
| 1 | Mob Rules |
| 2 | Children of the Sea |
| 3 | I |
| 4 | Bible Black |
| 5 | Time Machine |
| 6 | Fear |
| 7 | Falling Off the Edge of the World |
| 8 | Follow the Tears |
| 9 | Die Young |
| 10 | Heaven and Hell |
| 11 | Neon Knights |
| Blu-ray The Video Collection |
| 1 | Live From Radio City Music Hall (Full Concert) |
| 2 | Neon Nights: Live at Wacken (Full Concert) |
| 3 | 30th Anniversary Interviews |
| 4 | Ronnie James Dio Tribute |
| 5 | Heaven and Hell (Road Movie) |
| 6 | Hail the Gods of Metal |
| 7 | The Mob Rules (Meet the Mob) |
| 8 | Voodoo (Live at Radio City) |
